Ester of monoperoxy oxalic acid as polymerization initiators

Details Ester of monoperoxy oxalic acid as polymerization initiators Ester of monoperoxy oxalic acid as polymerization initiators

1989-05-16

1991-08-06

Henderson, Christopher

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526227, 5263442, C08F 436

Patent

active

050379151

ABSTRACT:
New dialkyl esters of monoperoxyoxalic acid which have a tertiary alkyl group in the perester part of the molecule while the other alkyl group is a long-chain, primary alkyl group. The compounds give rise to radicals at heating and are useful as initiators for the polymerization of ethylenically unsaturated monomers, particularly for the polymerization of vinyl chloride.

REFERENCES:
patent: 2608571 (1952-08-01), Rust et al.
patent: 2698863 (1955-01-01), Dickey
patent: 4455412 (1984-06-01), Lydiate
Journal of the American Chemical Society, vol. 97, No. 8, 16th Apr. 1975, pp. 2281-2283, F. R. Jensen et al., "Conversion of Alcohols to Halides by Homolytic Reactions".
Chem. Abstracts 104:225267h (Matisova-Rychla et al.).

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