Ester derivatives of lower alkene oligomers

Details Ester derivatives of lower alkene oligomers Ester derivatives of lower alkene oligomers

1990-12-11

1994-04-19

Dees, Jose G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

568909, C07C 6702

Patent

active

053046757

ABSTRACT:
An ester product consisting essentially of the acylation product of a mixture of near linear aliphatic 1-alkanols, said alkanols containing six to twenty carbon atoms and having a methyl to methylene branch ratio less than 0.25. These novel esters can be further converted to valuable 1-alkenes by pyrrolysis. In the preferred embodiments, esters are derived by acylation of C.sub.9 -C12 1-alkanols having a methyl to methylene branch ratio less than 0.18.
In the preferred method of synthesizing the esters, acylation is carried out using aliphatic carboxylic acid, anhydride, halide or ester as acylating agent, wherein the agent has 2 to 20 carbon atoms. For instance, the acylating agent may comprise acetic anhydride and to produce acetate esters.

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