Ester and method for production thereof as well as hydrolysis pr

Details Ester and method for production thereof as well as hydrolysis pr Ester and method for production thereof as well as hydrolysis pr

1992-01-30

1994-12-20

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560231, 554229, 435280, 23293R, C07C 6976

Patent

active

053747666

ABSTRACT:
This invention relates to a novel ester which presents as (CF 1) and a method for the production of the same as well as a process for hydrolysis and a method for the determination of an optical purity using this ester, and the object thereof is to provide an intermediate for the synthesis or various natural products, which has high stability, and the optical purity of which can readily be determined, according to the esterification of 1-oxo-5-hydroxymethyl-2-cyclohexene which is unstable to acids and alkalis. ##STR1##

REFERENCES:
Hauser, F. M. et al. J. Am. Chem. Soc. 1984, 106 1862-1863.
Shigefumi Kuwahara and Kenji Mori-Tetrahedron vol. 46, No. 24 pp. 8083-8092, 1990 (Synthesis of Both The Enantiomers of Hauptmann's Periplanone-A and Clarification Of The Structure Of Persoons's Periplanone-A).

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