Chemistry of inorganic compounds – Phosphorus or compound thereof – Halogen containing
Patent
1988-03-10
1990-02-20
Stoll, Robert L.
Chemistry of inorganic compounds
Phosphorus or compound thereof
Halogen containing
423302, 423304, 423386, 423462, C01B 2510
Patent
active
049024906
ABSTRACT:
Essentially pure and colorless N-(dichlorophosphoryl)trichlorophosphazene [P.sub.2 NOCl.sub.5 ] is prepared/purified under relatively moderate conditions, by reacting phosphorous pentachloride with ammonium chloride, treating the resulting medium of reaction, containing P.sub.3 NCl.sub.12, with SO.sub.2, and thin film evaporating the medium of reaction, advantageously in two stages, to eliminate SO.sub.2, POCl.sub.3 and SOCl.sub.2 values therefrom.
REFERENCES:
patent: 1356878 (1920-10-01), Newton
patent: 2925320 (1960-02-01), Kahler
patent: 3231327 (1966-01-01), Seglin et al.
Pagniez Guy
Potin Philippe
Atochem
Stoll Robert L.
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