Epoxy thermosets having improved toughness

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

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428209, 428901, 523445, 523458, 523466, 523468, 525113, 525389, 525396, 525415, 525423, 525438, 525468, 525504, 525523, 525525, 525526, 525906, 528 90, 528 93, 528109, 528119, 528129, 528315, C08L 6300, C08K 304, C08G 5950

Patent

active

046562079

ABSTRACT:
Disclosed is a stiff, tough thermoset composite, the composite comprising a crosslinked epoxy resin matrix and high strength filaments. The resin matrix comprises a glassy discontinuous phase dispersed in a glassy continuous phase that continues throughout the resin matrix. Volume fractions of the discontinuous phase are at least about 35% of the total volume of the continuous and discontinuous phases combined in exceptionally tough composites.
Also disclosed are novel resin compositions suitable for making these thermosets.

REFERENCES:
patent: 3920768 (1975-11-01), Kwiatkowski
patent: 3950451 (1976-04-01), Suzuki et al.
patent: 4330659 (1982-05-01), King et al.
patent: 4430473 (1984-02-01), Brode et al.
Sergeyev et al, Vysokomol Soyed A25 No. 6 1311-1315, 1983.
Development of Resins for Damage Tolerant Composites--A Systematic Approach, 29th National Sampe Symposium, Apr. 3-5, 1984, 422-436, Diamont and Moulton.
Addition of Polyethersulphone to Epoxy Resins--The British Polymer Journal, 15, 71-75 (1983).
Phase Separation in Epoxy Resins Containing Polyethersulphone--Bucknall and Partridge, Polymer, 24, 639-646 (1983).
Deformation and Fracture Behaviour of a Rubber-Toughened Epoxy: 1. Microstructure and Fracture Studies, Polymer, 24, 1341-1354 (1983), Kinloch, Shaw, Tod, and Hunston.
High Temperature Polymers, I-Sulfone Ether Diamines as Intermediates for Tractable High Temperature Polymers, Journal of Polymer Science, 12, 565-573 (1974), Kawakami, Kwiatkowski, Brode and Bedwin.

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