Epoxy monomers from sucrose

Details Epoxy monomers from sucrose Epoxy monomers from sucrose

1995-02-14

1996-11-05

Nagumo, Mark

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536124, 549525, 549531, 527300, 527303, 527312, 528405, 528406, 528407, C07H 100

Patent

active

055719074

ABSTRACT:
A method for producing sucrose-based epoxy monomers having one to eight epoxy groups per molecule of sucrose, which comprises reacting a mixture comprising: a sucrose monomer having an allyl-containing group on at least one of the hydroxyl groups, and a reagent or catalyst selected from molybdenum, tungsten, vanadium, titanium and peracid, in the presence of hydrogen peroxide or a derivative thereof, in relative amounts sufficient to produce a sucrose-based epoxy monomer. Monomers thus produced are also provided. The sucrose-based epoxy monomers can be cured to produce a sucrose-based epoxy resin. Such resins are useful, for example, as adhesives, composites and coatings.

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