Epoxy end-capped diolefin derivatives, polymers thereof, and pro

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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549512, 5253592, 528393, C08G 5902, C08G 5922, C08C 1906, C08C 1940

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049772201

ABSTRACT:
Epoxy end-capped oligomers of 1,3-diolefin compounds of Formula I ##STR1## These oligomers are formed by: (a) reacting a 1,3-diolefin compound having 4 to 12 carbon atoms per molecule with a difunctional initiator comprising anionic reactive sites to form an intermediate living oligomer comprising two anionic end groups; and
(b) reacting the intermediate living oligomer with a halohydrin compound to epoxidize the two anionic end groups and form the desired oligomer.
The oligomers are subsequently reacted with an epoxidizing agent to form a polymer having epoxy-derived linkages at regular intervals along the chain of the polymer.

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Makromol. Chem., vol. 179, pp. 551-555, Beinert et al.
Polymer Preprints, vol. 26, No. 1, Apr. 1985, pp. 241-243, Broske et al.
J. Polymer Science, vol. 20, pp. 2809-2817, Kennedy et al.

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