Epoxide isomerization process

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3518

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active

044967764

ABSTRACT:
Di-, tri- and tetra-substituted epoxides are isomerized to allylic alcohols in the presence of a metal alkoxide catalyst in which the metal is selected from early transition metals of Groups 1VA and VA and in the absence of a solvent.

REFERENCES:
patent: 4306099 (1981-12-01), Fetizon et al.
Eschinasi, E. H., Israel Journal of Chemistry, vol. 6, pp. 713-721, (1968).
Chemical Abstract, 70:78165x.

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