Epoxide isomerization catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Phosphorus or compound containing same

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502208, 502232, B01J 2714, B01J 27182, B01J 2108

Patent

active

054552150

ABSTRACT:
Improved catalysts for isomerizing epoxides to allylic alcohols are disclosed. The catalysts contain lithium phosphate supported on high-purity silica. The use of high-purity silica as a support results in improved epoxide conversion and allylic alcohol selectivity, and reduced by-product generation. The invention includes a process for isomerizing epoxides using the catalysts. The process is well-suited to the manufacture of allyl alcohol from propylene oxide.

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patent: 3285967 (1966-11-01), Schaeffer
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patent: 4720598 (1988-01-01), Scholte
patent: 5262371 (1993-11-01), Faraj
patent: 5292974 (1994-03-01), Faraj
Kirk-Othmer's Encyclopedia of Chemical Technology (1982), "Silica," vol. 20, pp. 748-817.

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