Epoxide isomerization catalysts

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 2956, C07C 3303

Patent

active

056000332

ABSTRACT:
Improved catalysts for isomerizing epoxides to allylic alcohols are disclosed. The catalysts contain lithium phosphate supported on high-purity silica. The use of high-purity silica as a support results in improved epoxide conversion and allylic alcohol selectivity, and reduced by-product generation. The invention includes a process for isomerizing epoxides using the catalysts. The process is well-suited to the manufacture of allyl alcohol from propylene oxide.

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