Epoxidation process using improved heterogeneous catalyst compos

Details Epoxidation process using improved heterogeneous catalyst compos Epoxidation process using improved heterogeneous catalyst compos

1998-04-15

2000-01-04

Rotman, Alan L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30119

Patent

active

060111623

ABSTRACT:
Highly active and selective epoxidation catalysts are prepared by combining silica or the like with a non-oxygenated hydrocarbon solution of titanium halide, removing solvent, calcining at an elevated temperature (preferably, in a substantially oxygen-free atmosphere), and, optionally, reacting with water and silylating. The resulting materials are useful heterogeneous catalysts for transforming olefins to epoxides using organic hydroperoxides.

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