Epoxidation of olefins with less stable organic hydroperoxides b

Details Epoxidation of olefins with less stable organic hydroperoxides b Epoxidation of olefins with less stable organic hydroperoxides b

1974-11-06

1976-09-28

Milestone, Norma S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252431R, C07D30120

Patent

active

039831434

ABSTRACT:
Method for the molybdenum-catalyzed epoxidation of less reactive olefins such as the alpha-olefins and alpha-substituted olefins with the less stable organic hydroperoxides to give good yields of the epoxide by employing a critical amount of a stabilizing agent consisting of a C.sub.3 to C.sub.9 secondary or tertiary monohydric alcohol.

REFERENCES:
patent: 3434975 (1969-03-01), Sheng et al.
patent: 3489775 (1970-01-01), DE Roch et al.
patent: 3502740 (1970-03-01), Zajacek et al.
patent: 3526645 (1970-09-01), Vangermain et al.
patent: 3538124 (1970-11-01), Sheng et al.
patent: 3649648 (1972-03-01), Fetterman

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