Epoxidation of olefins via certain manganese complexes

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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502167, B01J 3118

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active

055167381

ABSTRACT:
A method for epoxidizing olefins is provided wherein an olefin and an oxygenating agent are contacted together in the presence of a manganese complex catalyst having at least one manganese atom coordinated with a nitrogen-containing ligand such that the manganese atom to coordinated nitrogen atom is 1:3 and thereafter isolating the resultant epoxide product. Catalyst compositions are also provided formed from the adsorption of the manganese complex catalyst onto a solvent insoluble support.

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patent: 5246621 (1993-09-01), Favre et al.
J. Am. chem. Soc. (Wieghardt et al.), 1988, vol. 110, pp. 7398-7410.
J. Am. chem. Soc. (Wieghardt et al.), 1988, pp. 1145-1146.

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