Epoxidation of olefins by hydrogen peroxide

Details Epoxidation of olefins by hydrogen peroxide Epoxidation of olefins by hydrogen peroxide

1974-09-30

1976-04-27

Milestone, Norma S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D30112

Patent

active

039534804

ABSTRACT:
An oxirane compound is prepared by reacting an olefinically unsaturated compound with hydrogen peroxide in the presence both of (i) at least one lead compound, exemplarily triethyl lead hydroxide and also of (ii) at least one compound of a group IV-A, V-A or VI-A transition metal exemplarily tungsten hexacarbonyl. The epoxided products are useful in the manufacture of plastics, adhesives and the like.

REFERENCES:
patent: 3489775 (1970-01-01), Seree de Roch et al.
patent: 3597459 (1971-08-01), Mimoun et al.
patent: 3654317 (1972-04-01), Harrod et al.
patent: 3778451 (1973-12-01), Poite

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