Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Patent
1987-05-28
1989-07-04
Raymond, Richard L.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
C07D30119
Patent
active
048452513
ABSTRACT:
Complexes are made by reacting a solid ammoniummolybdate and a solid alkali metal molybdate with ethylene -glycol. Stripping of water of reaction subsequent to complex formation is preferred. The ratio of moles of alkylene glycol to total gram atoms of molybdenum should be in the range from about 7:1 to about 20:1 and the ratio of gram atoms of molybdenum in the ammonium molybdate to gram atoms of molybdenum in the alkali metal molybdenum should be in the range of about 1:1 to about 20:1. Solutions of the complexes are excellent catalysts for the reaction of propylene with an organic hydroperoxide such as tertiary butyl hydroperoxide to form propylene oxide and tertiary butyl alcohol.
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Keating Kenneth P.
Marquis Edward T.
Sanderson John R.
Park Jack H.
Priem Kenneth R.
Raymond Richard L.
Ries Carl G.
Russell Mark W.
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