Enzyme catalyzed synthesis of polyesters

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Preparing heterocyclic carbon compound having only o – n – s,...

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435134, 435135, C12P 1702, C12P 762

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active

051477912

ABSTRACT:
A method for synthesizing a polyester comprises reacting a diester and a dialcohol at approximately ambient temperature in the presence of an enzyme catalyst, preferably a lipase comprising porcine pancreatic lipase. The method is particularly adapted for enantioselective polymerization resulting in an optically active polyester. The polyesters preferably exhibit a weight average molecular weight, Mw, as measured by gel permeation chromatography of at least about 3000.

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