Enzymatic synthesis of polyesters

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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435183, 524700, 524704, 524770, C08G 6378, C12N 900

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active

059626240

ABSTRACT:
A linear polyester is made by a process reacting polyols comprising at least two primary alcohol groups and at least one secondary alcohol or amino group and a dicarboxylic acid or a dicarboxylic acid ester in the presence of an effective amount of a lipase derived from Candida cylindracea, Candida lipolytica, Candida rugosa, Candida antarctica, Candida utilis, Chromobacterium viscosum, Geotrichum viscosum, Geotrichum candidum, Mucor javanicus, Mucor miehei, Porcine pancreas, Pseudomonas species, specifically Pseudomonas fluorescens, Pseudomonas cepacia, Pseudomonas pseudoalkaligenes, Pseudomonas alkaligenes, Thermomyces species, Rhizopus arrhizus, Rhizopus delemar, Rhizopus niveus, Rhizopus oryzae, Rhizopus javanicus, Aspergillus niger, Penicillium roquefortii, Penicillium camembertii or an esterase derived from Bacillus species, specifically Bacillus thermoglucosidasius; Mucor miehei, Horse liver, Saccharomyces cerevisiae, Pigs liver or combinations thereof. The secondary OH or amino group of the polyol moiety is unreacted.

REFERENCES:
patent: 5478910 (1995-12-01), Russell et al.
Mezoul, et al., "Enzyme-Catalyzed Synthesis Of Aliphatic Polyesters In Organic Media: Study Of Transesterification Equilibrium Shift And Characterization Of Cyclic Compounds", Journal Of Polymer Science, Part A: Polymer Chemistry, vol. 33, John Wiley & Sons, Inc., 1995, pp. 2691-2698.
Okumura, et al., "Synthesis Of Ester Oligomer By Aspergillus niger Lipase", Agric. Biol. Chem., 48 (11), 1984, pp. 2805-2808.
Wu, et al., "Lipase-Catalyzed Polyester Synthesis", Biotechnology Techniques, vol. 10., No. 10, Oct., 1996, pp. 793-798.
Kobayashi, et al., "Dehydration Polymerization In Aqueous Medium Catalyzed By Lipase", Chemistry Letters 1997, The Chemical Society of Japan, p. 105.

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