Enzymatic production of optical isomers of 2-halopropionic acids

Details Enzymatic production of optical isomers of 2-halopropionic acids Enzymatic production of optical isomers of 2-halopropionic acids

1985-02-27

1986-07-22

Marantz, Sidney

Chemistry: molecular biology and microbiology

Process of utilizing an enzyme or micro-organism to destroy...

Resolution of optical isomers or purification of organic...

435136, 435141, C07P 4100, C12P 740, C12P 752

Patent

active

046019871

ABSTRACT:
A method of resolving racemic 2-halopropionic acids by lipase-catalyzed asymmetric esterification in an organic medium is disclosed.

REFERENCES:
"Lipase-Catalyzed Production of Optically Active Acids via Asymmetric Hydrolysis of Esters", Cambou, B. and Klibanov, A. M., Appl. Biochem. Biotech., 9, 255 (1984).
Abstract of Japanese Patent JP 57/94295 A2.
"Enzymatic Catalysis in Organic Media at 100.degree. C.", Zaks, A. and Klipanov, M. Science, 224, 1249 (1984).
"Preparative Production of Optically Active Esters and Alcohols Using Esterase-Catalyzed Stero-Specific Transesterfication in Organic Media", Cambou, B. and Klibanov, A. M., J. Am. Chem. Soc., 1984, 106 2687.

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