Enzymatic process for the enantioselective preparation of optica

Details Enzymatic process for the enantioselective preparation of optica Enzymatic process for the enantioselective preparation of optica

1992-09-01

1994-09-13

Robinson, Douglas W.

Chemistry: molecular biology and microbiology

Micro-organism, tissue cell culture or enzyme using process...

Preparing nitrogen-containing organic compound

435280, C12P 1300, C12P 4100

Patent

active

053468163

ABSTRACT:
Enantioselective process for the preparation of the S enantiomer of an optically active cyanohydrin by reacting an aldehyde or an asymmetric ketone with a cyanide group donor in the presence of an S-hydroxynitrile lyase in a diluent and isolating the cyanohydrin formed from the reaction mixture.

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Smitskamp-Wilms et al., Recl. Trav. Chim. Pays-Bas 110(05): 209-15 (1991).
Kobayashi et al., Chemistry Letters, 931-934 The Chemistry Society of Japan (1986).
Ognyanov et al., J. Am. Chem. Soc., 113(18) 6992-6996 (1991).
Selmar et al., Physiologia Plantarum, 75, 97-101 (1989).
Selmar et al., Analytical Biochemistry, 166, 208-211 (1987).
Westley et al., The Journal of Organic Chemistry, 33(10) 3978-3980 (1968).
Schurig et al., Angewandte Chemie, 102, 969-986 (1990).
Chemical Abstracts, 111, Ref: 132610u (1989).

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