Entangled single-wall carbon nanotube solid material and...

Stock material or miscellaneous articles – Web or sheet containing structurally defined element or... – Composite having voids in a component

Reexamination Certificate

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C428S314200, C428S315900, C428S319300, C428S319100, C428S220000, C423S44500R, C423S44500R, C002S002500

Reexamination Certificate

active

06899945

ABSTRACT:
Buckyrock is a three-dimensional, solid block material comprising an entangled network of single-wall carbon nanotubes (SWNT), wherein the block comprises greater than 75 wt % SWNT. SWNT buckyrock is mechanically strong, tough and impact resistant. The single-wall carbon nanotubes in buckyrock form are present in a random network of individual single-wall carbon nanotubes, SWNT “ropes” and combinations thereof. The random network of the SWNT or SWNT ropes can be held in place by non-covalent “cross-links” between the nanotubes at nanotube contact points. In one embodiment, SWNT buckyrock is made by forming a SWNT-water slurry, slowly removing water from the slurry which results in a SWNT-water paste, and allowing the paste to dry very slowly, such that the SWNT network of the SWNT-water paste is preserved during solvent evaporation. Buckyrock can be used in applications, such as ballistic protection systems, involving light-weight material with mechanical strength, toughness and impact resistance.

REFERENCES:
patent: WO 98/39250 (1998-09-01), None
patent: WO 00/17101 (2000-03-01), None
patent: WO 01/30694 (2001-05-01), None
patent: WO 02/39051 (2002-05-01), None
patent: WO 02/64868 (2002-08-01), None
patent: WO 02/64869 (2002-08-01), None
Yakobson et al., “Fullerene Nanotubes: C1,000,000 and Beyond,” American Scientist, vol. 85, pp. 324-337 (1997).
Dresselhaus et al., Science of Fullerenes and Carbon Nanotubes, San Diego: Academic Press, Ch. 19 (1996).
Chiang et al., “Purification and Characterization of Single-Wall Carbon Nanotubes (SWNTs) Obtained from the Gas-Phase Decomposition of CO (HiPco Process),” Journal of Physical Chemistry B, vol. 105, pp. 8297-8301 (2001).
Chiang et al., “Purification and Characterization of Single-Walled Carbon Nanotubes,” Journal of Physical Chemistry B, vol. 105, pp. 1157-1161 (2001).
Popov, et al., “Superhard phase composed of single-wall carbon nanotubes”, Physical Review B, vol. 65 (2002), pp. 33408-1-33408-4.

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