Enolic ethers of adipic dialdehyde and method for preparing the

Details Enolic ethers of adipic dialdehyde and method for preparing the Enolic ethers of adipic dialdehyde and method for preparing the

1973-01-23

1976-03-16

Gallagher, Richard J.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2604656, 260473R, 260521B, 260602, 260611A, 260613R, 260615R, C07C12166, C07C12134, C07C 4726, C07C 4314

Patent

active

039445917

ABSTRACT:
Enolic monoether and diether of adipic dialdehyde such as 6-methoxy-5-hexene-1-al, 1,6-dimethoxy-1,5-hexadiene, 1,6-bis-(2 hydroxy propoxy)-1,5-hexadiene are prepared by heating to a sufficiently high temperature for a Cope rearrangement, e.g., 150.degree. to 450.degree. C. of the corresponding monoether or diether of 1,5-hexadiene-3,4-diol.

REFERENCES:
Berson et al., "J.A.C.S.," Vol. 86, pp. 5019-5020 (1964).
Viola et al., "J.A.C.S.," Vol. 87, pp. 1150 & 1151 (1965).
Chuche et al., C. R. Acad. Sci., Paris, Tome 262, pp. 567-570 (1966).

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