Enhancement of shape selectivity of zeolites

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – Activating treatment

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502 85, 502 77, 423328, 208120, B01J 2938

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active

046787666

ABSTRACT:
A method is provided for enhancing the shape selectivity of a crystalline zeolite having a silica-to-alumina mol ratio greater than 10. The method consists of treating the zeolite with an ammonium fluoride solution at moderately elevated temperature, in the absence or in the presence of a matrix. The products are useful as shape-selective sorbents, and also as shape-selective catalysts for organic reactions including catalytic dewaxing.

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