Enhanced photocatalytic oxidation of organics using a porous tit

Liquid purification or separation – Processes – Utilizing electrical or wave energy directly applied to...

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210758, 210763, 210205, 4221863, C02F 132, B01J 1908

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active

061173371

ABSTRACT:
A method and apparatus for mineralizing organic contaminants in water or air provides photochemical oxidation in a unique two-phase or three-phase boundary system formed in each pore of a TiO.sub.2 membrane in a photocatalytic reactor. In the three-phase system, gaseous oxidant, liquid contaminant, and solid semiconductor photocatalyst having a metal catalyst disposed thereon meet and engage in an efficient oxidation reaction. The porous membrane has pores which have a region wherein the meniscus of the liquid varies from the molecular diameter of water to that of a capillary tube resulting in a diffusion layer that is several orders of magnitude smaller than the closest known reactors. The photocatalytic reactor operates effectively at ambient temperature and low pressures.

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