Enhanced diisobutene production in the presence of methyl tertia

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585515, 585526, 585820, 585830, 585832, C07C 204

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active

043755763

ABSTRACT:
In the liquid phase reaction of isobutene in the presence of resin cation exchange resins with itself in a C.sub.4 hydrocarbon stream to form dimers, the formation of higher polymers, oligomers, and co-dimer by-products is suppressed by the presence of 0.0001 to 1 mole per mole of isobutene of methyl tertiary butyl ether.

REFERENCES:
patent: 4071567 (1978-01-01), Ancillotti et al.
patent: 4215011 (1980-07-01), Smith
patent: 4218569 (1980-08-01), Chase et al.
patent: 4242530 (1980-12-01), Smith
patent: 4313016 (1982-01-01), Manning
Haag, Kinetic & Catalysis, #73 vol. 63, pp. 140-147.

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