Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...
Patent
1981-07-27
1983-03-01
Gantz, Delbert E.
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
By addition of entire unsaturated molecules, e.g.,...
585515, 585526, 585820, 585830, 585832, C07C 204
Patent
active
043755763
ABSTRACT:
In the liquid phase reaction of isobutene in the presence of resin cation exchange resins with itself in a C.sub.4 hydrocarbon stream to form dimers, the formation of higher polymers, oligomers, and co-dimer by-products is suppressed by the presence of 0.0001 to 1 mole per mole of isobutene of methyl tertiary butyl ether.
REFERENCES:
patent: 4071567 (1978-01-01), Ancillotti et al.
patent: 4215011 (1980-07-01), Smith
patent: 4218569 (1980-08-01), Chase et al.
patent: 4242530 (1980-12-01), Smith
patent: 4313016 (1982-01-01), Manning
Haag, Kinetic & Catalysis, #73 vol. 63, pp. 140-147.
Chemical Research & Licensing Co.
Gantz Delbert E.
Johnson Kenneth H.
Pal Asokkumar
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