Energy polymerizable compositions containing organometallic init

Details Energy polymerizable compositions containing organometallic init Energy polymerizable compositions containing organometallic init

1991-11-26

1993-03-02

Dees, Jose G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 60, 556142, 556144, C07F 1702, C07F 1300

Patent

active

051911019

ABSTRACT:
An energy polymerizable composition and process therefore, comprising a cationically polymerizable material and a catalytically effective amount of an ionic salt of an organometallic complex cation as polymerization initiator, said ionic salt of an organometallic complex cation being capable of adding an intermediate strengeth nucleophile or upon photolysis capable of liberating at least one coordination site, said metal in said organometallic complex cation being selected from elements of Periodic Groups IVB, VB, VIB, VIIB, and VIIIB are disclosed. Certain of the organometallic metallic polymerization initiators are novel cationic salts.

REFERENCES:
patent: 3705129 (1972-12-01), Murio et al.
patent: 3709861 (1973-01-01), Anderson
patent: 3714006 (1973-01-01), Anderson
patent: 3736264 (1973-05-01), Cheuvin
patent: 3794576 (1974-02-01), Watt
patent: 3867354 (1975-02-01), Betts et al.
patent: 4026705 (1977-05-01), Crivello et al.
patent: 4058400 (1977-11-01), Crivello
patent: 4080274 (1978-03-01), Schlesinger
patent: 4086091 (1978-04-01), Cella
patent: 4237242 (1980-12-01), Frankel
Inorg. Chem., 1, 933 (1962).
Inorg. Chem., 51, 1177 (1966).
Brown, et al., Die Agnew. Makromol. Chemie, 50, 9-14 (1976).
Helling et al., "New, Improved Synthesis of Bisbenzeneiron (II) Hexafluorophosphate and Related Compounds," Journal of the Chemical Society: Chemical Communications, 1971, p. 930.
Tetrahedron, 34, 3047 (1978).
J. Organometallic Chem., 186, 265 (1980).
Woodhouse, et al., J. Am. Chem. Soc., 100, 996 (1978).
Woodhouse, et al., J. Am. Chem. Soc., 104, 5586 (1982).
Kaeriyama, et al., J. Polym. Sci., Chem. Ed. 10, 2833 (1972).
J. Chem. Soc. (Chem. Comm.) 930 (1971).
J. Organometallic Chem., 1, 307 (1964).
Inorganic Synth., 6, 132 (1960).
J. Organometallic Chem., 12, P18 (1968).
J. Chem. Soc. (Chem. Comm.), 311 (1981).
Angew. Chemie, 72, 919 (1960).
Inorg. Chem., 5, 1837 (1966).
J. Chem. Soc., D. 1677 (1975).
J. Inorg. Nucl. Chem., 1, 165 (1955).
J. Am. Chem. Soc., 99, 4726 (1977).
Organometallic Synthesis, A. R. B. King, Academic Press, NY 1965.
Gazz. Chim. Ital., 88, 1170 (1958).
McGinnis, "Organometallic Redox", Polymer Preprints 15, No. 2, Sep. 1974 Amer. Chem. Soc., pp. 302-305.
Ledwith, "New Initiation Systems", Makromol. Chem. Sup. 3, 348-358 (1979).

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