Energy efficient synthesis of boranes

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Treating electrode – diaphram – or membrane during synthesis

Reexamination Certificate

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C423S294000, C423S342000

Reexamination Certificate

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07837852

ABSTRACT:
The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.

REFERENCES:
patent: 6524542 (2003-02-01), Amendola et al.
patent: 2003/0092877 (2003-05-01), Amendola et al.
patent: 2004/0241507 (2004-12-01), Schubert et al.
patent: 2008/0175781 (2008-07-01), Thorn et al.

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