Energy conservation and pollution abatement at phosphorus furnac

Chemistry of inorganic compounds – Phosphorus or compound thereof – Elemental phosphorus

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23313R, 44 10C, 71 32, 71 48, 71 6405, 252 1, 422243, 423167, C01B 2501

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active

043729290

ABSTRACT:
A process and product of waste recovery at phosphorus furnaces is disclosed wherein small sized discrete particles of carbonaceous material or beneficiated phosphate ore are mixed with a mineral acid, an alkaline fluid and water, and the reacted mixture is tumbled in a horizontal cylinder at a temperature below that at which the carbonaceous material oxidizes to form agglomerates which are then indurated to discrete particulate size as desired for a charge component; the agglomerates are fed to a phosphorus smelting furnace together with other materials needed to make elemental phosphorus, furnace gases are cooled with recirculating water, a side stream of the water is taken off, treated, and used as feedstock in fluid fertilizers. Apparatus is disclosed for agglomerating coke and phosphate and; further, for measuring the abrasion and shatter resistance of agglomerates.

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"Phosphorus Furnace Operations, How are they affected by various types of phosphate charges?", by J. C. Barber et al., Journal of Metals, (Dec. 1962), pp. 1-5.
"Waste Effluent; Treatment and Reuse", by J. C. Barber, Chemical Engineering Progress, vol. 65, No. 6, (Jun. 1969), pp. 70-73.

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