Ammunition and explosives – Powder form – Having burning inhibiting means
Reexamination Certificate
2000-09-27
2002-02-12
Nelson, Peter A. (Department: 3641)
Ammunition and explosives
Powder form
Having burning inhibiting means
C102S288000, C102S289000
Reexamination Certificate
active
06345577
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to coating gun propellant grains with a slow burning energetic material for use as a deterrent coating. More particularly, the slow burning energetic material improves the progressivity of conventional gun propellants without reducing the gun propellants chemical energy.
2. Brief Description of the Related Art
Soluble low-energy or inert materials, such as dibutyl phthalate, methyl centralite, triacetin and paraplex, have conventionally been used as propellant grain deterrent coatings. Lower burning rates are achieved through use of these low-energy or inert plasticizers. These materials improve the burning properties of the propellant grain by allowing the propellant to burn faster later in the ballistics cycle. While these inert materials lower the burning rate of the gun propellant, the materials decrease the chemical energy of the propellant due to their low energy content which diminishes the total chemical energy of the propellant, thus reducing the overall performance of the propellant.
In view of the foregoing, there is a need in the art to improve the burning properties of conventional gun propellants without decreasing the energy of the propellant. The present invention addresses this and other needs.
SUMMARY OF THE INVENTION
Energetic materials are used as a deterrent coating material for gun propellant.
The present invention includes a gun propellant composition comprising a gun propellant grain component and an energetic deterrent coating composed of at least one slow burning material coated onto the propellant grain component, wherein the at least one slow burning energetic material reduces the burn rate at the surface of the propellant grain and causes the propellant to burn progressively.
The present invention also includes a method of manufacturing a gun propellant composition having an energetic deterrent coating comprising the steps of forming a propellant grain component, dissolving an energetic deterrent coating into a solvent and applying the dissolved energetic deterrent onto the formed propellant grain.
Additionally, the present invention includes a gun propellant composition product made by the process comprising the steps of providing a gun propellant composition having a propellant grain component and an energetic deterrent coating composed of at least one slow burning energetic material coated onto the propellant grain component, wherein the at least one slow burning energetic material reduces the burn rate at the surface of the propellant grain and causes the propellant to burn progressively and burning the gun propellant.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
The present invention includes a gun propellant composition having an energetic deterrent coating on the outside of a propellant grain component. The present invention improves the progressivity of conventional gun propellants by incorporating a slow burning energetic material as deterrent coatings onto propellant grains. Through the use of an energetic material, the burning properties of the propellant grain are improved without the loss of chemical energy.
The propellant grain component may include single base, double base, triple base, nitramine, or other like propellants. Propellants having abase of nitrocellulose are generally referred to as single base propellants. Mixtures of nitrocellulose and nitroglycerin are referred to as a double base propellant. When the base is a mixture of nitrocellulose, nitroglycerin and nitroguanidine, the propellant is referred to as a triple base propellant. Propellants may also comprise a binder component and a nitramine. The nitramine is usually present in an amount from 30% to 85% by weight depending upon the propellant characteristics desired. Typical nitramine used in gun propellant formulations is cyclotrimethylenetrinitramine (RDX). The configuration of the propellant grain, usually cylindrical, can vary in diameter and length, preferably ranging from about 0.25 inches to about 1.0 inch, and preferably having one or more perforations, preferably ranging from about one perforation (single-perf) to about 19 perforations (19-perf).
The propellant binder can be selected from those binders known in the art such as single-base binders, double-base binders or inert binders plasticized with energetic plasticizers. Gun propellant binders having a wide range of burning rates are available with the proper selection of binder determinable by those skilled in the art in light of the disclosure herein. Energetic plasticizers can be compounded with the inert binders in amounts up to 50% to 60% by weight. Representative energetic plasticizers are organic nitrates such as triethylene glycol dinitrate (TEGDN), trimethylol ethane trinitrate (TMETN), nitroglycerine (NG), and the like.
The energetic deterrent coating of the present invention comprises at least one slow burning energetic material. These slow burning energetic materials reduce the burn rate at the surface of the propellant grain and cause the propellant to bum progressively. The energetic deterrent coating comprises a crystalline solid. Preferably these crystalline solids comprise one or more organic compounds which exhibit a fast self-sustaining chemical reaction that releases large quantities of heat and energy. Self-sustaining compounds are those compounds that sustain a chemical reaction without requiring additional oxidizer or fuel. Organic compounds useful in energetic deterrent coatings of the present invention preferably include compounds possessing amino, nitro, nitroamino, hydrazino, azido, nitroxyethylamino, and nitroxyethylnitramino functional groups.
Suitable energetic materials preferably include high nitrogen compounds such as dihydrazine tetrazine, insensitive munitions materials such as 2,6-diamino-3,5-dinitropyrazine-1-oxide, diaminodinitroethylene, analogs of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB), and other like slow burning energetic materials, including for example dihydrazinotetrazene (HZTZ), 1,3,5-tris(2-nitroxyethylamino)-2,4,6-triniobenzene (PITNE), and 1-(2-nitroxyethylamino)-3-(2-nitroxyethylnitramino)-2,4,6-trinitrobenzene (PINANE). Other useful energetic materials of the present invention which have good energy, and acceptable burning rates, and are slightly soluble in appropriate coating solvents include, but are not limited to diamino dinitropyrazine-1-oxide (LLM-105) and diamino dinitroethylene (FOX-7). Preferred energetic materials include HZTZ, TATB, PINANE, PITNE, LLM-105 and FOX-7.
TABLE 1.
Organic Energetic Deterrent Coatings Compounds
Hear for
Energetic
Chemical
%
Density
Formation
Deterrent
Chemical Name
Formula
Nitrogen
(g/cc)
(kcal/mol)
HZTZ
Dihydrazinotetrazine
C
2
H
6
N
8
78
1.68
+128
TATB
Triaminorinitrobenzene
C
6
H
6
N
6
O
6
32
1.93
±35
PINANE
Nitroxyethylamino
23
1.74
—
Nitroxyethylnitramino)
C
10
H
11
N
7
O
12
Trinitrobenzene
PITNE
Tris(2-nitroxyethylamino)
C
12
H
15
N
9
O
15
24
1.69
—
Trinitrobenzene
LLM-105
Diamino Dinitropyrazine-1-
C
4
H
4
N
6
O
5
39
1.91
−3
oxide
FOX-7
Diamnio Dinitroethylene
C
2
H
4
N
4
O
4
38
1.88
−30
Preferably, the energetic deterrent coating comprises a high density deterrent. High density, high energy materials that exhibit some solubility in low volatility solvents may be used. High density deterrents, for the purposes of the present invention, include a density of from about 1.6 g/cm
3
or greater, with preferred densities of from about 1.6 g/cm
3
to about 2.0 g/cm
3
. For proper application of the energetic deterrent coating, the slow burning energetic material comprises a soluble material. Solubility of the slow burning energetic material preferably ranges from about 0.05 percent weight per weight of solvent or greater, with a more preferred range of from about 0.05 percent weight per weight of solvent to about 5 percent weight per weight of a solvent. Useful solvents are compositions that are not detrimental to propellant grain integrity, and include without limitation, water, alcohol, ether, ethyl a
Cramer Randall J.
Mitchell Steve
Peters Susan
Simmons Ronald
Homer Mark
Nelson Peter A.
The United States of America as represented by the Secretary of
LandOfFree
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