Enantioselective hydrocyanation of aromatic vinyl compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitriles

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C07C25310

Patent

active

051753359

ABSTRACT:
The invention provides a process for enantioselective hydrocyanation of aromatic vinyl compounds which produces nonracemic mixtures of chiral, arylpropionitriles; novel carbohydrate phosphorus and nickel catalyst compositions; and optically pure (S)-(-)-2-(6-metehoxy-2-naphthalene)propionitrile.

REFERENCES:
patent: 3496215 (1970-02-01), Drinkard et al.
patent: 3496217 (1970-02-01), Drinkard, Jr. et al.
patent: 3496218 (1970-02-01), Drinkard, Jr. et al.
patent: 3631191 (1971-12-01), Kane et al.
patent: 3655723 (1972-04-01), Drinkard, Jr.
patent: 3766237 (1973-10-01), Chia et al.
patent: 3798256 (1974-03-01), King et al.
patent: 3846461 (1974-11-01), Shook, Jr.
patent: 3847959 (1974-11-01), Shook, Jr. et al.
patent: 3903120 (1975-09-01), Shook, Jr. et al.
patent: 3925445 (1975-12-01), King et al.
W. Nugent et al., J. Org. Chem., 50: pp. 5370-5372, (1985).
C. Tolman et al., Adv. Catal., vol. 33: pp. 1-46, (1985).
M. Hodgson et al., Organometallics, 7: pp. 1761-1766, (1988).
W. Jackson, et al., Aust. J. Chem., 35: pp. 2069-2075 (1982).
M. Baker, et al., J. Chem. Soc. Commun. p. 1292 (1991).
S. Harusawa, et al., Synthetic Communications, 14(14): pp. 1365-1371 (1984).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Enantioselective hydrocyanation of aromatic vinyl compounds does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Enantioselective hydrocyanation of aromatic vinyl compounds, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Enantioselective hydrocyanation of aromatic vinyl compounds will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1888808

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.