Enantioselective bioreduction using yeast

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Preparing oxygen-containing organic compound

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549445, C12P 700, C07D31744

Patent

active

061210269

ABSTRACT:
The invention relates to a class of enantiomerically pure intermediates represented by Formula I, where X is F, Cl, Br, or I, and a novel enantioselective bioreductive process using yeast to form these intermediates, which are useful in the synthesis of endothelin antagonists, and the like. ##STR1##

REFERENCES:
patent: 4147799 (1979-04-01), Obase et al.
patent: 5717116 (1998-02-01), Saito et al.
Obase, H. et al "1-(3,4-methylenedioxyphenyl)-2-alkylaminoethanol Derivatives" CA 78:136260 (1973).
Saito, K. et al "Process for Producing (R)-Styrene Oxides" CA 125:273737 (1991).

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