Enantioselective addition of hydrocarbons to alpha,beta-unsatura

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568343, 568350, 568351, 568388, 568396, C07C 4500

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active

051625865

ABSTRACT:
The conjugate addition of hydrocarbon equivalents to alpha,beta-unsaturated carbonyl compounds using a series of novel catalysts is described. The catalysts comprise copper(I) complexes with ligand systems comprising either tropocoronand macrocycles or N,N'-dialkylsubstituted aminotroponeimines.

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