Enantioselective addition of hydrocarbons to alpha,beta-unsatura

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 28, C07F 108

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054400627

ABSTRACT:
The conjugate addition of hydrocarbon equivalents to alpha,beta-unsaturated carbonyl compounds using a series of novel catalysts is described. The catalysts comprise copper(I) complexes with ligand systems comprising either tropocoronand macrocycles or N,N'-dialkylsubstituted aminotroponeimines.

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