Enantiomeric enrichment of cyanohydrins

Chemistry: molecular biology and microbiology – Process of utilizing an enzyme or micro-organism to destroy... – Resolution of optical isomers or purification of organic...

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435128, 549422, 549491, 554113, 558354, 558410, 558423, 558430, 558431, 558432, 558433, 558434, 558451, 546330, C07C25332, C07C25334, C12P 1300, C12P 4100

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active

RE0352306

ABSTRACT:
A method of enantiomerically enriching chiral cyanohydrins is disclosed that involves selective cleavage of the unwanted enantiomer into its cleavage products HCN and the corresponding aldehyde or ketone by use of an enantioselective dehydrocyanation catalyst, coupled with simultaneous removal of at least one of the dehydrocyanation products.

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