Emissive polymers and devices incorporating these polymers

Compositions – Organic luminescent material containing compositions – Synthetic resin containing

Reexamination Certificate

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C252S582000, C252S301160, C422S068100, C422S050000, C422S082050, C257S040000

Reexamination Certificate

active

07943062

ABSTRACT:
The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

REFERENCES:
patent: 4356429 (1982-10-01), Tang
patent: 4687732 (1987-08-01), Ward et al.
patent: 4927768 (1990-05-01), Coughlin et al.
patent: 4946890 (1990-08-01), Meador
patent: 4992302 (1991-02-01), Lindmayer
patent: 5155149 (1992-10-01), Atwater et al.
patent: 5194393 (1993-03-01), Hugl et al.
patent: 5236808 (1993-08-01), Smothers
patent: 5244813 (1993-09-01), Walt et al.
patent: 5254633 (1993-10-01), Han et al.
patent: 5364797 (1994-11-01), Olson et al.
patent: 5414069 (1995-05-01), Cumming et al.
patent: 5451683 (1995-09-01), Barrett et al.
patent: 5511547 (1996-04-01), Markle et al.
patent: 5512490 (1996-04-01), Walt et al.
patent: 5532129 (1996-07-01), Heller
patent: 5540999 (1996-07-01), Yamamoto et al.
patent: 5546889 (1996-08-01), Wakita et al.
patent: 5554747 (1996-09-01), Sharma et al.
patent: 5556524 (1996-09-01), Albers
patent: 5563056 (1996-10-01), Swan et al.
patent: 5565322 (1996-10-01), Heller
patent: 5580527 (1996-12-01), Bell et al.
patent: 5585646 (1996-12-01), Kossovsky et al.
patent: 5591787 (1997-01-01), Schlennert et al.
patent: 5597890 (1997-01-01), Jenekhe
patent: 5607864 (1997-03-01), Ricchiero et al.
patent: 5629353 (1997-05-01), Steckle, Jr. et al.
patent: 5679773 (1997-10-01), Holmes
patent: 5700696 (1997-12-01), Chandross et al.
patent: 5705348 (1998-01-01), Meade et al.
patent: 5709994 (1998-01-01), Pease et al.
patent: 5710187 (1998-01-01), Steckle, Jr. et al.
patent: 5710197 (1998-01-01), Fischer et al.
patent: 5723218 (1998-03-01), Haugland et al.
patent: 5869592 (1999-02-01), Gagnéet al.
patent: 5925517 (1999-07-01), Tyagi et al.
patent: 6020426 (2000-02-01), Yamaguchi et al.
patent: 6259277 (2001-07-01), Tour et al.
patent: 6509110 (2003-01-01), Salbeck et al.
patent: 6556335 (2003-04-01), Jones et al.
patent: 6589731 (2003-07-01), Chen et al.
patent: 6605693 (2003-08-01), Becker et al.
patent: 6713298 (2004-03-01), McDevitt et al.
patent: 6962757 (2004-03-01), Epstein et al.
patent: 6743640 (2004-06-01), Whitten et al.
patent: 6783814 (2004-08-01), Swager et al.
patent: 7186355 (2007-03-01), Swager et al.
patent: 7208122 (2007-04-01), Swager et al.
patent: 2002/0040805 (2002-04-01), Swager
patent: 2002/0150697 (2002-10-01), Swager et al.
patent: 2002/0177136 (2002-11-01), McBranch et al.
patent: 2003/0054413 (2003-03-01), Kumaraswamy et al.
patent: 2003/0134959 (2003-07-01), Hancock et al.
patent: 2004/0043251 (2004-03-01), Epstein et al.
patent: 2004/0121337 (2004-06-01), Deans et al.
patent: 2004/0175768 (2004-09-01), Kushon et al.
patent: 2004/0235184 (2004-11-01), Swager
patent: 2004/0241768 (2004-12-01), Whitten et al.
patent: 2005/0014160 (2005-01-01), Kumaraswamy et al.
patent: 2006/0024707 (2006-02-01), Deans et al.
patent: 19744792 (1999-04-01), None
patent: 19806037 (1999-09-01), None
patent: 0442123 (1991-08-01), None
patent: 0581058 (1994-02-01), None
patent: 1011154 (2000-06-01), None
patent: 06-322078 (1994-11-01), None
patent: 89/000593 (1989-01-01), None
patent: 98/005693 (1995-02-01), None
patent: 95/016681 (1995-06-01), None
patent: 99/19419 (1999-04-01), None
patent: 99/057222 (1999-11-01), None
patent: 00/053655 (2000-09-01), None
patent: 01/057140 (2001-08-01), None
patent: 02/016463 (2002-02-01), None
patent: 2003/048226 (2003-06-01), None
patent: 2004/057014 (2004-07-01), None
patent: 2006/081345 (2006-08-01), None
Davey, Andrew P. et al., New Rigid Backbone Conjugated Organic Polymers with Large Fluorescence Quantum Yields, J. Chem. Society., Chem. Commun., 1995, 1433-1434.
Moroni, M. et al., Rigid Rod Conjugated Polymers for Nonlinear Optics. 3. Intramolecular H Bond Effects on Poly (phenyleneethynylene) Chains, Macromolecules, 1997, 30, 1964-1972.
Achyuthan et al., “Fluorescence Superquenching of Conjugated Polyelectrolytes: Applications for Biosensing and Drug Discovery,” J. Mat. Chem., 2005, 15:2648.
Bergstedt et al., “Superquenching of Fluorescent Polyelectrolytes and its Applications for Chemical and Biological Sensing,” Proc. SPIE 2001, 4279:94.
Brabec et al., “Plastic Solar Cells,” Adv. Funct. Mater, 2001, 11(1):15-26.
Chen et al., “Highly sensitive biological and chemical sensors based on reversible fluorescence quenching in a conjugated polymer,” PNAS, 1999, 96(22):12287-12292.
Chen et al., “Surfactant-induced Modification of Quenching of Conjugated Polymer Fluorescence by Electron Acceptors: Applications for Chemical Sensing,” Chem. Phys. Lett., 2000, 330:27.
Chen et al., “Tuning the Properties of Conjugated Polyelectrolytes through Surfactant Complexation,” J. Am. Chem. Soc., 2000, 122:9302-9303.
Cotts et al., “Equilibrium Flexibility of a Rigid Linear Conjugated Polymer,” Macromolecules 1996, 29:7323-7328.
Dagani, R. “A Better Sensor for Nerve Gas,” C&E News, Mar. 10, 2003, p. 12.
Davey et al., “New Rigid Backbone Conjugated Organic Polymers with Large Fluorescence Quantum Yields,” J. Chem. Society., Chem. Commun., 1995, pp. 1433-1434.
Deans et al., “A Poly(p-phenyleneethynylene) with a Highly Emissive Aggregated Phase,” J. Am. Chem. Soc., 2000, 122:8565-856.
Fan et al., “Beyond Superquenching: Hyper-Efficient Energy Transfer from Conjugated Polymers to Gold Nanoparticles,” PNAS 2003, 100(11):6297.
Fan et al., “High-Efficiency Fluorescence Quenching of Conjugated Polymers by Proteins,” J. Am. Chem. Soc., 2002, 124:5642.
Fan et al., “Photoluminescence Quenching of Water-Soluble, Conjugated Polymers by Viologen Derivatives: Effect of Hydrophobicity,” Langmuir 2003, 19:3554. Published on Web, Mar. 19, 2003.
Fiesel et al., “On the Solid State Aggregation of Chiral Substituted Poly(para-phenylene)s (PPPs),” Synthetic Metals 1999, 102:1457.
Fiesel et al., “A chiral poly(para-phenyleneethynylene) (PPE) derivative,” Macromol. Rapid Commun., 1998, 19(8):427-431.
Fiesel et al., “Aggregation-induced CD effects in chiral poly(2,5-dialkoxy-1,4-phenylene)s,” Acta Polym., 1998, 49:445-449.
Fu et al., “Alternating Poly(PyridylVinylenePhenyleneVinylene)s: Synthesis and Solid State Organizations,” Tetrahedron, 1997, 53(45):15487-15494.
Gaylord et al., “DNA detection using water-soluble conjugated polymers and peptide nucleic acid probes,” PNAS, 2002, 99(17):7245.
Gaylord et al., “DNA detection using water-soluble conjugated polymers and peptide nucleic acid probes,” PNAS, 2002, 99(17):10954-10957.
Gaylord et al., “DNA Hybridization Detection with Water-Soluble Conjugated Polymers and Chromophore-Labeled Single-Stranded DNA,” J. Am. Chem. Soc., 2003, 125:896.
Gaylord et al., “SNP Detection Using Peptide Nucleic Acid Probes and Conjugated Polymers: Applications in Neurodegenerative Disease Identification,” PNAS, 2005, 102(1):34.
Gaylord et al., “Water-Soluble Conjugated Oligomers: Effect of Chain Length and Aggregation on Photoluminescence-Q

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