Elongate bismuth system superconductor having aligned 2212 phase

Superconductor technology: apparatus – material – process – Processes of producing or treating high temperature... – Process of making wire – tape – cable – coil – or fiber

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505430, 505704, 505742, 505782, 427 62, 29599, 1741251, H01L 3924, H01B 1204

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active

054017173

ABSTRACT:
This invention is related to the preparation of an elongate conductor having a silver sheath, and a core of an aligned polycrystalline oxide superconductor having the approximate formula Bi.sub.2-x Pb.sub.x Sr.sub.2-a L.sub.a+b Ca.sub.1-b Cu.sub.2 O.sub.y where y is from 7.5 to 8.5, and L is a lanthanide. A powder mixture is formed comprised of a first portion of a superconducting bismuth oxide compound that can be reaction-sintered to form the core oxide superconductor, and a second portion of oxides suitable for reacting with the first portion to form the core oxide superconductor. An elongate body is formed having a silver sheath, and a core of the mixture. The body is deformed to align the first portion, and heated to reaction-sinter the first and second portions to form the core oxide superconductor.

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Wai Lo and B. A. Glowacki, A Study of the Formation Processes of the 2212 Phase in the Bi-based Superconductor Systems, Physica C 193 (1992) pp. 253-263.
S. X. Dou, H. K. Liu, M. H. Apperley, K. H. Song and C. C. Sorrell, Critical Current Density in Superconducting Bi-Pb-Sr-Ca-Cu-O Wires and Coils, Supercond. Sci. Technol 3 (1990) pp. 138-142.
Yamada et al, "Properties of Ag-Sheathed Bi-Pb-Sr-Ca-Cu-O Superconducting Tapes Prepared by the Intermediate Pressing Process", Jpn. J. Appl. Phys. vol. 29, No. 3, Mar. 1990, pp. L456-L458.

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