Electrosynthesis of sodium dithionite

Chemistry: electrical and wave energy – Processes and products

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204129, C25B 102, C25B 114

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active

049768352

ABSTRACT:
An aqueous sulfuric acid anolyte solution is circulated through the anode compartment of an electrolytic cell, and an aqueous NaHSO.sub.3 catholyte solution is circulated through its cathode compartment, while maintaining an anolyte and catholyte temperature range of 20.degree.-25.degree. C., a catholyte pH range of 4.6 to 5.8, and a reduction potential of -1.25 to -1.50 V versus Ag.degree./AgCl, to produce an aqueous solution of Na.sub.2 S.sub.2 O.sub.4. Optimum pH is maintained by small additions of an alkali to the catholyte solution for electrolysis and solution stability.

REFERENCES:
patent: 3748238 (1973-07-01), Heit et al.
patent: 3905879 (1975-09-01), Eng et al.
patent: 3920551 (1975-11-01), Cook et al.
patent: 4144146 (1979-03-01), Leutner et al.
patent: 4743350 (1988-05-01), Cawlfield et al.

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