Electrolysis: processes – compositions used therein – and methods – Electrolytic coating – Coating moving substrate
Reexamination Certificate
2001-10-13
2003-11-18
Wong, Edna (Department: 1753)
Electrolysis: processes, compositions used therein, and methods
Electrolytic coating
Coating moving substrate
C205S148000, C205S291000, C205S296000
Reexamination Certificate
active
06649038
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates generally to the field of electroplating. In particular, the present invention relates to the electroplating of electronic devices having very small recessed features.
Electroplating articles with copper coatings is generally well known in the industry. Electroplating methods involve passing a current between two electrodes in a plating solution where one electrode is the article to be plated. A common plating solution would be an acid copper plating solution containing (1) a dissolved copper salt (such as copper sulfate), (2) an acidic electrolyte (such as sulfuric acid) in an amount sufficient to impart conductivity to the bath and (3) additives (such as surfactants, brighteners, levelers and suppressants) to enhance the effectiveness and quality of plating. See generally U.S. Pat. Nos. 5,068,013; 5,174,886; 5,051,154; 3,876,513; and 5,068,013 for a discussion of copper plating baths.
Over time, a number of improvements in electroplating techniques have been made as the articles to be plated evolved in degree of difficulty and standards for plating increased. However, even with such improvements circumstances exist that can lead to plating defects.
Copper plating technology has been particularly important in the manufacture of computer circuit boards. More specifically, during circuit board manufacture, copper electrical connections are provided between various board layers by plating board through holes whereby a thin conductive copper conductive is first applied, typically using electroless copper plating techniques, followed by electroplating copper from acid copper solutions. Copper plating is also employed in circuit board manufacture to plate outer layers where final circuitry is defined. For such applications, panel plating is typically employed, where the full circuit board surface is copper plated followed by photodefining circuitry with a photoresist and then etching in a subtractive process. Alternatively an additive process can be employed, where copper circuits are produced by plating between lines defined by a resist relief image.
More recently, copper plating also has been employed in semiconductor chip manufacture to provide chip interconnections, replacing aluminum conductors. Industry continually demands enhanced performance, including ultra large-scale integration and faster circuits. Consequently, chip interconnects are required at dimensions of 200 nm and less. At such geometries, the resistivity of aluminum (theoretically 2.65×10
−8
ohm/meter at room temperature) is considered too high to allow the electronic signal to pass at required speeds. Copper, with a theoretical resistivity of 1.678×10
−8
ohm/meter, is a more suitable material to meet the next generation of semiconductor microchips.
Typical processes for defining semiconductor chip interconnects, particularly aluminum interconnects, have involved reactive ion etching of metal layers, e.g. a process that includes metal deposition, photolithographic patterning, line definition through reactive ion etching and dielectric deposition. However, in copper-based systems, reactive ion etching is not practical as a result of the paucity of copper compounds with vapor pressures sufficient to enable removal of the copper as may be desired.
Consequently, alternative strategies have developed, such as the Damascene process. That process starts with deposition of dielectric typically by chemical vapor deposition of silicon materials or organic dielectrics followed by curing, or spin coating silicon materials or organic dielectrics. Patterning by photolithographic processes and reactive ion etching defines the vias and trenches (interconnects) in the dielectric. Barrier layers are then formed by chemical vapor deposition or other methods to isolate the copper lines from the dielectric. Copper is then deposited and excess material removed by chemical or mechanical polishing processes.
Although conventional copper plating systems can be suitable for plating vias and trenches as small as 300 nm with 4:1 aspect ratios, defects such as seams, voids and inclusions can occur with conventional methods when attempting to plate features that are smaller or have higher aspect ratios. Such defects can occur as a result of conformal copper plating, i.e. where all targeted surfaces are plated at the same rate such that the sidewalls of a via or trench plate together forming a seam or a demarcation of disruption where the copper grains are separated and will not anneal to form a continuous copper wire. Defects also will occur at the top rim of a via hole, where electronic charge density can concentrate and result in rapid copper growth that closes off the via before the via is filled sufficiently with metal. Such inadequate metal fill can result in inclusion and voids, disrupting the ability of the plated metal to carry a coherent signal.
A semiconductor wafer is generally plated with excess copper. During the process of manufacturing an integrated circuit, a semiconductor wafer is often polished to remove the excess unwanted materials on the surface of the wafer. Polishing generally takes the form of chemical-mechanical planarization (“CMP”) wherein a chemically active slurry is used in conjunction with a polishing pad.
Modern electrolyte and additive packages for filling of advanced interconnects generally use sulfuric acid, cupric sulfate, chloride ion, and two or more organic additives to assist in the formation of void free fill. Optimized fill proceeds by a 2-step fill sequence referred to as bottom-up fill. The first step is conformal fill, which electroplates copper uniformly over the wafer surface and inside features. Conformal fill transitions to the second step, bottom-up fill, once a critical feature dimension is reached during the fill process. The one consequence of bottom-up fill is the creation of excessive topography (bumps) over dense and sparse arrays. This added topography can be as high as 10 kÅ and is difficult to planarize during the CMP process.
There is thus a need for methods of electrodepositing copper on an electronic device that provide bottom-up fill of small recessed features without the creation of excessive topography over the surface of the electronic device.
SUMMARY OF THE INVENTION
It has been surprisingly found that the method of the present invention provides good bottom-up fill of recessed features in a substrate using conventional copper electroplating baths without creating excessive topography of the copper layer on the surface of the substrate. Such plated copper layer is also thinner as compared to conventional copper plating methods. Thus, the present method provides a copper layer that is more suitable for chemical mechanical planarization than that from conventional plating methods.
In one aspect, the present invention provides a method for depositing copper on a substrate including the steps of: a) providing a substrate having apertures, the substrate rotating at a speed of about 0 to 10 rpm; b) contacting the substrate with an electroplating solution including a soluble copper salt and an electrolyte for a period of time sufficient to deposit copper into the apertures, the electroplating solution having a flow rate of about 0 to 1 gpm; c) increasing the rotation of the substrate to about 20 rpm or greater; and d) contacting the substrate with the electroplating solution for a period of time sufficient to deposit a desired thickness of copper, the flow rate of the electroplating solution being about 2 gpm or greater.
In a second aspect, the present invention provides a method for manufacturing an electronic device including the steps of: a) providing a substrate having apertures, the substrate rotating at a speed of about 0 to 10 rpm; b) contacting the substrate with an electroplating solution including a soluble copper salt and an electrolyte for a period of time sufficient to deposit copper into the apertures, the electroplating solution having a flow rate of about 0 to 1 gpm; c) increas
Calvert Jeffrey M.
Mikkola Robert D.
Morrissey Denis
Cairns S. Matthew
Shipley Company L.L.C.
Wong Edna
LandOfFree
Electroplating method does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Electroplating method, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Electroplating method will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-3184130