Electronically conductive lithia doped oxide ceramics for use in

Chemistry: electrical current producing apparatus – product – and – Fluid active material or two-fluid electrolyte combination... – Active material in molten state

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252518, H01M 1039

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active

044566310

ABSTRACT:
This invention relates to electrically conductive ceramic materials suitable for use at high temperatures and in the presence of corrosive environments, e.g., the sodium-sulfur battery. The ceramic material comprises chromium oxide (Cr.sub.2 O.sub.3) doped with at least 0.02 mole percent lithia, wherein the chromium oxide contains less than about 0.5 mole percent of any impurity selected from the group consisting of sodium oxide and potassium oxide, based on moles of chromium oxide. The doped chromium oxide can be used as coatings on metal or metal alloy so as to form corrosion resistant current collectors which may be container/current collectors.

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"Electrical Conduction in Fe.sub.2 O.sub.3 and Cr.sub.2 O.sub.3," D. de Cogan and G. A. Lonergan, Solid State Communications, vol. 15, pp. 1517-1519, 1974.

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