Electricity: electrical systems and devices – Electrostatic capacitors – Fixed capacitor
Reexamination Certificate
2001-04-16
2004-04-13
Reichard, Dean A. (Department: 2831)
Electricity: electrical systems and devices
Electrostatic capacitors
Fixed capacitor
C361S312000, C361S313000, C361S321100, C361S321500, C501S139000, C501S140000
Reexamination Certificate
active
06721164
ABSTRACT:
The invention relates to a passive component, in particular a multilayer component, comprising a dielectric and at least one electrode.
Many components having a multilayer structure are manufactured in the electronics industry. Among them are, for example, multilayer capacitors, antennas, actuators, and varistors. Multilayer capacitors are manufactured in the greatest quantities.
Ceramic multilayer components are usually manufactured in that green ceramic substrate foils alternating with layers of a metal paste for the inner electrodes are stacked on components, which are usually dielectric, whereupon the stack of ceramic and metal layers is sintered.
The quality of a multilayer component is determined both by the chemical composition of the materials used for the dielectric and for the electrodes and by the manufacturing conditions. It is first and foremost the sintering conditions which play a part in the manufacturing conditions. Various, mutually opposed oxidation and reduction reactions may take place during sintering in dependence on the sintering atmosphere. Thus, for example, barium titanate and its derivatives becomes semiconducting during sintering in a reducing atmosphere. They are unsuitable as dielectrics in this state. Sintering of the multilayer capacitors under oxidizing conditions can take place only if the electrode material consists of rhodium, palladium, or platinum. Rhodium and platinum, however, are very expensive, their cost price may account for up to 50% of the total. The development rather tends towards the use of the much cheaper metals such as Ni, Cu, Ag, or alloys thereof instead of rhodium and platinum. These metals, however, oxidize when sintered under oxidizing conditions.
There is a particular demand for ceramic materials which can be used in combination with cheaper metals, such as nickel, copper, or silver, as temperature-stable NP0 materials, which are widely used in the field of telecommunication. The use of silver electrodes is especially attractive because the internal resistance has an increasing influence at the frequencies of above 500 MHz used in telecommunication because of the so-called skin effect. It is only electrodes of copper, silver, gold, and aluminum which have sufficiently low values for the internal resistance which render possible a use at higher frequencies. Capacitors with low, but accurate capacitance values are particularly interesting for these applications.
A reduction of the sintering temperature to below 900° C., which renders possible the use of silver electrodes, is problematic because the dielectric materials with high melting points are to be sintered with highly reactive glasses or other compounds of low melting points. This in its turn may lead to reactions between the various phases, which will then change the temperature specification of the dielectric materials used.
The invention has for its object to provide an electronic component, in particular a multilayer component, which can be inexpensively manufactured.
This object is achieved by means of an electronic component with a dielectric and at least two electrodes, characterized in that the dielectric comprises a composite consisting of a dielectric ceramic material and an organic polymer.
Usually, passive ceramic components are sintered for strengthening the dielectric. This leads to a shrinkage, i.e. a density increase in the dielectric which will be very different in dependence on the nature of the material, the particle size distribution of the basic powder, and the reaction conditions (sintering temperature, sintering time, sintering atmosphere). In the component according to the invention, the strengthening of the dielectric is achieved by means of a polymer. The dielectric ceramic material is for this purpose first mixed with the monomer of a suitable polymer, whereupon the monomer is polymerized. Sintering is rendered unnecessary thereby.
Preferably, the organic polymer is insoluble in water.
The use of a water-insoluble polymer prevents changes in the properties and shape of the passive component and/or the dielectric which could be caused by the penetration of moisture.
It is furthermore preferred that the polymer comprises a polyimide, polyethylene, polycarbonate, or polyurethane.
These polymers wet the dielectric ceramic material and are all insoluble in water.
It may be preferred that the dielectric ceramic material has a low temperature coefficient.
Electronic components, in particular capacitors and antennas, whose dielectric has a low temperature coefficient are widely used in the field of telecommunications. The temperature specification of the dielectric is not changed because of the low temperatures in the manufacture of the passive component.
It is particularly favorable when the electrodes comprise Ag, Au, Cu, Al, or alloys of these metals.
Since sintering at high temperatures is not necessary, inexpensive metals which would be oxidized under the usual sintering conditions can be used as the electrode material. In addition, these metals have a low effective series resistance.
It is preferred that the electronic component is chosen from the group comprising capacitors, antennas, actuators, and varistors.
The invention further relates to a method of manufacturing an electronic component with a dielectric and at least two electrodes, in which method
the dielectric ceramic material and a monomer of a polymer are mixed together,
the mass obtained is formed,
the monomer is partly or completely polymerized, and
the electrodes are provided.
It may be preferred that a second polymerization step is carried out after the electrodes have been provided.
A typical manufacturing process for a multilayer component with printed metal layers comprises the following steps:
1. manufacture of a suspension from a ceramic powder, a solvent, a dispersing agent, a binder, a liquefier, etc.,
2. drawing out of the suspension into layers,
3. drying of the layers so as to obtain green ceramic foils,
4. printing of the green ceramic foils with a structured metal layer,
5. stacking of the foils,
6. laminating the stack,
7. separating into individual green products,
8. driving out of the binder by heating,
9. sintering,
10. providing the external contact paste and baking of the outer contacts.
The method according to the invention renders most of the above steps, in particular the sintering step, of this manufacturing process unnecessary. Not only does this simplify and shorten the method, it also reduces the cost.
It is preferred in all embodiments that the polymerization is thermally initiated.
The polymerization of the monomer is thermally initiated by means of temperatures below 400° C. These low temperatures during manufacture on the one hand lead to a product of stable shape, while on the other hand the manufacturing cost and the CO
2
emission are reduced.
It is furthermore preferred that the quantity m of monomer used lies between 3% by weight≦m≦20% by weight in relation to the quantity of dielectric ceramic material used.
The dielectric constant &egr; can be adjusted to a desired value by means of the mixing ratio of dielectric ceramic material and polymer in the composite material.
The invention also relates to a dielectric ceramic compound which comprises a composite of a dielectric ceramic material and an organic polymer.
A passive component of stable shape which is not limited to a planar geometry, such as, for example, a dielectric rod antenna, may be formed with the use of a dielectric ceramic compound which comprises a composite of a dielectric ceramic material and an organic polymer, and by means of the manufacturing method according to the invention.
The invention further relates to a filter arrangement with an electronic component which comprises a dielectric and at least two electrodes, wherein the dielectric comprises a composite of a dielectric ceramic material and an organic polymer.
The invention will now be explained in more detail below with reference to three embodiments.
To manufacture an electronic component according to the inv
Albertsen Knuth
Groen Wilhelm-Albert
Schlenker Tilman
Ha Nguyen T.
Reichard Dean A.
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