Electron emission device and display apparatus using the same

Electric lamp and discharge devices – With luminescent solid or liquid material – Vacuum-type tube

Reexamination Certificate

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C313S309000, C313S310000

Reexamination Certificate

active

06404124

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to an electron emission device, and more particularly to an electron emission display device which has a plurality of electron emission devices arranged in an image display array, for example, in a matrix form.
2. Description of the Related Art
Conventionally, in field electron emission display apparatuses, a Field Emission Display (FED) is known as a planar emission display device equipped with an array of cold cathode electron emission sources which does not require cathode heating. The emission principle of, for example, an FED using Spindt-type cold cathodes of minute protrusions is as follows: Its emission principle is like a Cathode Ray Tube (CRT), although this FED has a cathode array of Spindt-type protrusions which is different from that of CRT. In the FED, electrons are drawn into a vacuum space by means of each gate electrode spaced apart from the Spindt-type cathode, and the electrons are made to impinge upon the fluorescent substance that is coated on a transparent anode, thereby causing light emission.
This FED, however, has a problem of low production yield because the manufacture of the minute Spindt-type emitter arrays as a cold cathode is complex and involves many processes.
There is also known an electron emission device with electron emission devices of metal-insulator-metal (MIM) structure as a planar electron emission source. The electron emission device with the MIM structure comprises an Al underlayer as a base electrode, an Al
2
O
3
insulator layer with about 10 nm thickness, and a Au overlayer, as a top electrode with about 10 nm thickness which are formed in order on the substrate. In the case that this MIM device is placed under an opposing electrode in a vacuum, when a voltage is applied between the Al underlayer and the Au overlayer and, at the same time, an acceleration voltage is applied to the opposing electrode, then some of electrons emit out of the Au overlayer and reach the opposing electrode. However, even the electron emission device with the MIM structure does not yet provide a sufficient amount of emitted electrons.
To improve these disadvantages of emission of the MIM device, it is conventionally considered that there is a necessity to make the Al
2
O
3
insulator layer thinner by about several nanometers and make the Al
2
O
3
insulator layer with a uniform quality so that the interface between the Al
2
O
3
insulator layer and the Au overlayer is more uniform.
To provide a thinner and more uniform insulator layer, for example, an attempt has been made to control the anodized current by using an anodization method thereby to improve the electron emission characteristics, as in the invention described in Japanese Patent Application kokai No. Hei 7-65710.
OBJECT AND SUMMARY OF THE INVENTION
The present invention has been made in view of the above circumstances, and thus an object thereof is to provide an electron emission device having an electron emitting efficiency high enough to stably emit electrons at a low voltage applied thereto, and moreover a display apparatus including a flat panel display device which employs a plurality of such electron emission devices.
Furthermore, when the plural electron emission devices are used correspondingly to many pixels in a dots matrix for a flat panel display device in view of various technical applications, there is a problem that some of the devices provide erroneous light emission of non-selected pixels caused by erroneous electron radiations due to electrical leak. Another object of the invention is thus to provide an electron emission device with a high reliability for restricting the erroneous light emission and a display apparatus using the same.
The present invention provides an electron emission device which comprises:
an electron-supply layer made of metal or semiconductor and disposed on an ohmic electrode;
an insulator layer formed on the electron-supply layer; and
a thin-film metal electrode formed on the insulator layer,
characterized in that said electron-supply layer has a rectifier function layer, whereby the electron emission device emits electrons when an electric field is applied between the electron-supply layer and the thin-film metal.
According to the electron emission device having the structure mentioned above, said rectifier function layer includes at least one junction selected from a group consisting of a p-n junction or p-i-n junction composed of semiconductor layers and Schottky junction composed of a semiconductor layer and a metal layer.
According to the electron emission device having the structure mentioned above, said rectifier function layer is disposed at an interface between said ohmic electrode and said electron-supply layer.
According to the electron emission device having the structure mentioned above, said rectifier function layer is disposed at an intermediate region of said electron-supply layer.
According to the electron emission device having the structure mentioned above, said rectifier function layer is disposed at an interface between said insulator layer and said electron-supply layer.
According to the electron emission device having the structure mentioned above, said rectifier function layer includes a p-n junction or p-i-n junction of semiconductors, in which a p-type layer thereof serves as said electron-supply layer and is in contact with said insulator layer, so that said rectifier function layer is disposed between said insulator layer and said ohmic electrode.
According to the electron emission device having the structure mentioned above, said rectifier function layer includes a Schottky junction of semiconductor and metal, in one case, when a semiconductor layer is p-type the p-type semiconductor layer serves as said electron-supply layer and is in contact with said insulator layer, in another case, when a semiconductor layer is n-type a metal layer of the Schottky junction serves as said electron-supply layer and is in contact with said insulator layer, so that said rectifier function layer is disposed between said insulator layer and said ohmic electrode.
According to the electron emission device having the structure mentioned above, said insulator layer is made of dielectric and has a film thickness of 50 nm or greater.
According to the electron emission device having the structure mentioned above, said ohmic electrode is made of titanium nitride.
The present invention further provides an electron emission display device which comprises:
a pair of a back substrate and an optically transparent front substrate opposing to each other with a vacuum space interposed therebetween;
a plurality of electron emission devices, each of said electron emission devices including an electron-supply layer made of metal or semiconductor, formed on ohmic electrodes formed on a surface of said back substrate proximate to said vacuum space, an insulator layer formed on said electron-supply layer, and a thin-film metal electrode formed on said insulator layer and facing said vacuum space; and
said front substrate including collector electrodes formed on its surface proximate to said vacuum space, and fluorescent material layers formed on said collector electrodes,
wherein said electron-supply layer has a rectifier function layer.
In the electron emission display device according to the invention, said rectifier function layer includes at least one junction selected from a group consisting of a p-n junction or p-i-n junction composed of semiconductor layers and Schottky junction composed of a semiconductor layer and a metal layer.
In the electron emission display device according to the invention, said rectifier function layer is disposed at an interface between said ohmic electrode and said electron-supply layer.
In the electron emission display device according to the invention, said rectifier function layer is disposed at an intermediate region of said electron-supply layer.
In the electron emission display device according to the invention, said rectifier fun

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