Electrolytic silver refining process and apparatus

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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204106, 204130, 204111, 204252, 204213, 75101BE, 208308, C25C 120

Patent

active

046701150

ABSTRACT:
In an electrolytic silver refining process, crude silver is anodically dissolved while refined silver is cathodically deposited and at the accompanying (impurity) metals are selectively extracted from the used (spent) electrolyte and transferred to an aqueous phase. The used electrolyte is enriched in silver and accompanying metals are cathodically deposited and thus removed from the electrolyte. For this purpose, a specific electrolysis cell is provided. The cell being preferably a diaphragm cell with an anionic diaphragm. The extraction of the accompanying metals is achieved by liquid membrane permeation, preferably combined with solvent extraction.

REFERENCES:
patent: 3224873 (1965-12-01), Swanson
patent: 3410794 (1968-11-01), Li
patent: 3975244 (1976-08-01), Hunter
patent: 4374713 (1983-02-01), Natansohn et al.
patent: 4443305 (1984-04-01), Haynes
patent: 4468303 (1984-08-01), Griffin et al.
"Liquid-Membrane-Permeation, A Hydrometallurgical Process", leaflet (no other information available).
Li and Schrier, "Liquid Membrane Water Treating," Recent Developments in Separation Science, 1972, pp. 163-174.
Draxler and Marr, "Emulsion Liquid Membranes," pp. 1-29 and Figures.

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