Electrolytic reduction of alumina

Chemistry: electrical and wave energy – Processes and products

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204241, 204244, 204245, 204247, C25C 306, C25C 308, C25C 312

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active

048657018

ABSTRACT:
Alumina is reduced to molten aluminum in an electrolytic cell containing a molten electrolyte bath composed of halide salts and having a density less than alumina and aluminum and a melting point less than aluminum. The cell comprises a plurality of vertically disposed, spaced-apart, non-consumable, dimensionally stable anodes and cathodes. Alumina particles are dispersed in the bath to form a slurry. Current is passed between the electrodes, and oxygen bubbles form at the anodes, and molten aluminum droplets form at the cathodes. The oxygen bubbles agitate the bath and enhance dissolution of the alumina adjacent the anodes and inhibit the alumina particles from settling at the bottom of the bath. The molten aluminum droplets flow downwardly along the cathodes and accumulate at the bottom of the bath.

REFERENCES:
patent: 3562136 (1971-02-01), De Varda et al.
patent: 3647673 (1972-03-01), De Varda et al.
patent: 3730859 (1973-05-01), De Varda
patent: 3930967 (1976-01-01), Alder
patent: 4592812 (1986-06-01), Beck et al.
patent: 4681671 (1987-07-01), Duruz

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