Electrolytic protection of chlorine dioxide

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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C25B 100

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active

047675101

ABSTRACT:
Chlorine dioxide is formed by an autocatalytic electrochemical process from highly acidic chlorate solution containing a residual concentration of chlorine dioxide. Cathodic current is applied to the solution by an electrode which does not otherwise catalyze the chemical formation of chlorine dioxide from the acidic chlorate solution. High purity chloride dioxide is obtained while half the acid is consumed and half the water is produced as compared with a conventional chemical chlorine dioxide generating process.

REFERENCES:
patent: 4362707 (1982-12-01), Hardee et al.
patent: 4426263 (1984-01-01), Hardee et al.
Hardee--"The Electrochemical Generation of Chlorine Dioxide Utilizing Electrolytic Oxide Coatings", Extended Abstracts, vol. 85-1, pp. 617 to 618, The Electrochemical Society, 1985.

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