Electrolytic production of hydrogen peroxide using bipolar membr

Chemistry: electrical and wave energy – Processes and products

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204101, 204129, C25B 130

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active

053586093

ABSTRACT:
A method and apparatus for producing hydrogen peroxide in caustic solution utilizing an electrolytic cell having electrolytes, preferably, alkaline in both anode and cathode compartments separated by a bipolar membrane which splits water into hydrogen ions and hydroxyl ions. Electrolysis of oxygen which diffuses through a gas-diffusion cathode forms peroxide in catholyte while hydrogen ions generated within the bipolar membrane migrate into the catholyte. Peroxide can be produced in the catholyte as a cell product having a caustic to peroxide ratio of less than 1.0 at five percent peroxide, by weight.

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SRI International, Report No. 68B, Mar. 1992--Yu--Ren Chin.
"The Use of Gas Diffusion Electrodes in the On-Site Generation of Oxidants and Reductants"--Fifth International Forum on Electrolysis in the Chemical Industry Sponsored by the Electrosynthesis Company, Inc., Nov. 10-14, 1991, Fort Lauderdale, Fla., P. C. Foller et al.

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