Electrolytic preparation of 3,6-dichloropicolinic acid

Chemistry: electrical and wave energy – Processes and products

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C25B 300

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044976976

ABSTRACT:
The rate of production of 3,6-dichloropicolinic acid by reduction of tetrachloropicolinic acid in basic aqueous solution in a given cell can be considerably increased if a trichloropicolinic acid is added to the tetrachloropicolinic acid feed in substantially greater proportions than can result from in-situ reduction of the tetrachloro acid. Preferably, the trichloro acid is obtained by acid hydrolysis of by-products of symmetrical tetrachloropyridine manufacture by chlorination/chlorinolysis of 6-chloro-2-(trichloromethyl)pyridine.

REFERENCES:
patent: 4217185 (1980-08-01), Kyiacon

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