Electrolytic oxidation process

Details Electrolytic oxidation process Electrolytic oxidation process

1976-03-10

1977-06-28

Andrews, R. L.

Chemistry: electrical and wave energy

Processes and products

204292, C25B 302, C25B 1104

Patent

active

040324168

ABSTRACT:
Dialkyldithiocarbamates are electrolytically oxidized to tetraalkylthiuram disulfides in a direct current electrolytic cell divided into a cathode compartment and an anode compartment separated from each other by a cationic membrane. The anode is stationary and has active surfaces of shiny platinum. Tetraalkylthiuram disulfides are obtained in high yield and in high degree of purity. The product tetraalkylthiuram disulfides are useful as vulcanization accelerators, fungicides, and seed treating agents.

REFERENCES:
patent: 2385410 (1945-09-01), Gardner
patent: 3313717 (1967-04-01), Kowata et al.

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