Electrolytic method to make alkali alcoholates using ion...

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Preparing organic compound

Reexamination Certificate

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C205S451000, C205S452000, C205S453000, C205S454000, C205S457000

Reexamination Certificate

active

08075758

ABSTRACT:
Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. An alkali ion conducting solid electrolyte configured to selectively transport alkali ions is positioned between the anolyte compartment and the buffer compartment. An alkali ion permeable separator is positioned between the buffer compartment and the catholyte compartment. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.

REFERENCES:
patent: 3197392 (1965-07-01), Silversmith et al.
patent: 3730857 (1973-05-01), Tripp
patent: 3964983 (1976-06-01), Eisenbach et al.
patent: 4217184 (1980-08-01), Kuck et al.
patent: 4250000 (1981-02-01), Kuck et al.
patent: 4857665 (1989-08-01), Hinrichs et al.
patent: 4990413 (1991-02-01), Lee et al.
patent: 5246551 (1993-09-01), Pletcher et al.
patent: 5258106 (1993-11-01), Habermann et al.
patent: 5286354 (1994-02-01), Bard et al.
patent: 5290404 (1994-03-01), Toomey
patent: 5290405 (1994-03-01), Joshi et al.
patent: 5389211 (1995-02-01), Sharifian et al.
patent: 5425856 (1995-06-01), Buckholtz et al.
patent: 5437774 (1995-08-01), Laustsen
patent: 5575901 (1996-11-01), Hulme et al.
patent: 5578189 (1996-11-01), Joshi
patent: 5580430 (1996-12-01), Balagopal et al.
patent: 5968326 (1999-10-01), Yelon et al.
patent: 5985388 (1999-11-01), Tomita et al.
patent: 6004445 (1999-12-01), Genders et al.
patent: 6190407 (2001-02-01), Ogle et al.
patent: 6221225 (2001-04-01), Mani
patent: 6333093 (2001-12-01), Burrell et al.
patent: 6398938 (2002-06-01), Merk et al.
patent: 6573205 (2003-06-01), Myers et al.
patent: 6770187 (2004-08-01), Putter et al.
patent: 6805787 (2004-10-01), Bess et al.
patent: 2003/0106805 (2003-06-01), Horn
patent: 2005/0177008 (2005-08-01), Balagopal et al.
patent: 2005/0204612 (2005-09-01), Connemann et al.
patent: 2005/0262760 (2005-12-01), Lawson et al.
patent: 2006/0169594 (2006-08-01), Balagopal et al.
patent: 2006/0226022 (2006-10-01), Balagopal et al.
patent: 2007/0138020 (2007-06-01), Balagopal et al.
patent: 2007/0158205 (2007-07-01), Balagopal et al.
patent: 2007/0167642 (2007-07-01), Oku et al.
patent: 2008/0142373 (2008-06-01), Joshi et al.
patent: 2008/0173540 (2008-07-01), Joshi et al.
patent: 2008/0173551 (2008-07-01), Joshi et al.
patent: 2008/0245671 (2008-10-01), Balagopal et al.
patent: 2009/0056200 (2009-03-01), Joshi
patent: 2009/0057162 (2009-03-01), Balagopal et al.
patent: 2009/0178928 (2009-07-01), Groos et al.
patent: 139528 (1980-01-01), None
patent: 3346131 (1985-06-01), None
patent: 3702052 (1988-07-01), None
patent: 19603181 (1997-04-01), None
patent: 10360758 (2005-07-01), None
patent: 0146771 (1985-07-01), None
patent: 0559400 (1993-09-01), None
patent: 0826794 (1998-03-01), None
patent: 1155927 (1969-06-01), None
patent: 37469 (1985-12-01), None
patent: 53011199 (1978-02-01), None
patent: 59067379 (1984-04-01), None
patent: 07196561 (1995-08-01), None
patent: 103535 (1993-06-01), None
patent: WO-9627697 (1996-09-01), None
patent: WO-03014272 (2003-02-01), None
Young, “International Search Report for PCT/US07/00968 sent Oct. 1, 2007”,1-2.
Young, “Written Opinion for PCT/US07/00968 sent Oct. 1, 2007”,1-5.
Young, “International Search Report for PCT/US06/48746 sent Oct. 1, 2007”,1-2.
Young, “Written Opinion for PCT/US06/48746 sent Oct. 1, 2007”,1-4.
Phasge, Arun “Final Office Action for U.S. Appl. No. 11/449,953”, (Nov. 17, 2009).
Phasge, Arun “Final Office Action for U.S. Appl. No. 11/396,057”, (Jul. 23, 2009).
Phasge, Arun “Non-Final Office Action for U.S. Appl. No. 11/396,057”, (Dec. 24, 2009).
Phasge, Arun “Final Office Action for U.S. Appl. No. 11/010,822”, (Jul. 10, 2009).
Phasge, Arun “Non-Final Office Action for U.S. Appl. No. 11/010,822”, (Dec. 28, 2009).
Gregg, Nicholas “European Search Report”, European Application No. 06847897.3, PCT App. No. PCT/US2006048746,(Sep. 16, 2009), 1-4.
Young, International Search Report for PCT/US07/25541 sent Mar. 17, 2008, 1-2.
Young, Written Opinion for PCT/US07/25541 sent Mar. 17, 2008, 1-6.
Young, Lee W., “International Search Report”, (Jul. 7, 2008),1-2.
Young, Lee W., “Written Opinion of the International Searching Authority”, (Jul. 7, 2008),1-5.
Young, Lee W., “International Search Report”, (Dec. 18, 2008),1-2.
Young, Lee W., “Written Opinion of the International Searching Authority”, (Dec. 18, 2008),1-5.
Young, Lee W., “International Search Report”, (Apr. 24, 2009),1-3.
Young, Lee W., “Written Opinion of the International Searching Authority”, (Apr. 24, 2009),1-5.
Phasge, Arun S., “Office Action for U.S. Appl. No. 11/449,953”, (Apr. 7, 2009),1-9.
Phasge, Arun S., “Office Action for U.S. Appl. No. 11/396,057”, (Oct. 10, 2008),1-8.
Hinrichs, et al., “Abstract of DE3702052”, Patent Answer 14 of 19 in enclosed search by Science IP, (Jul. 14, 1988), 11.
Phasge, Office Action for U.S. Appl. No. 11/010,822 sent Jun. 30, 2008, 1-6.
Alamo, J. “Chemistry and properties of solids with the [NZP] skeleton”,Solid State Ionics, vol. 63-65, (1993), 547-561.
Balagopal, S. et al., “Selective Sodium Removal From Aqueous Waste Streams with NaSICON Ceramics”,Separation and Purification Technology, 15 (1999), 231-237.
Bentzen, J. J., et al., “The preparation and characterization of dense, highly conductive Na5GdSi4O12nasicon (NGS)”,Materials Research Bulletin, vol. 15, (1980), 1737-1745.
Boilot, J.P. et al., “Stoichiometry-Structure-Fast Ion Conduction in the NaSICON Solid Solution”,Solid State Ionics, 28-30 (1988), North-Holland, Amsterdam, 403-410.
Delmas, C. et al., “Crystal chemistry of the Na1+xZr2-xLx(PO4)3(L = Cr, In, Yb) solid solutions”,Materials Research Bulletin, vol. 16, (1981), 285-290.
Fujitsu, S. et al., “Conduction paths in sintered ionic conductive material Na1+xYxZr2-x(PO4)3”,Materials Research Bulletin, vol. 16, (1981), 1299-1309.
Goodenough, J.B. et al., “Fast Na+-Ion Transport in Skeleton Structures”,Mat. Res. Bull., vol. 11, 1976. Pergamon Press, Inc. Printed in the United States, 203-220.
Hong, H.Y-P. et al., “Crystal Structures and Crystal Chemistry in the System Na1+xZr2SixP3-xO12”, Mat. Res. Bull., vol. 11, 1976. Pergamon Press, Inc. Printed in the United States., 173-186.
Miyajima, Y. et al., “Ionic conductivity of NASICON-type Na1+xMxZr2-xP3O12(M: Yb, Er, Dy)”,Solid State Ionics, vol. 84, (1996), 61-64.
Saito, Y. et al., “Ionic Conductivity of NASICON-type conductors Na1.5M0.5Zr1.5(PO4)3(M: Al3+, Ga3+, Cr3+, Sc3+, Fe3+, In3+, Yb3+, Y3+)”,Solid State Ionics, vol. 58, (1992), 327-331.
Shannon, R.D. et al., “Ionic Conductivity in Na5YSi4O12Type Silicates”,Inorganic Chemistry, vol. 17, No. 4 (1978), 958-964.
Shimazu, K. et al., “Electrical conductivity and Ti4+ion substitution range in NASICON system”,Solid State Ionics, vol. 79, (1995), 106-110.
Sutija, Davor et al., “Ceramic Cleansers: Environmental Uses of Sodium Super-Ionic Conducting Ceramics”,The Electrochemical Society Interface, Winter 1996, vol. 5, No. 4, 26-30.
Van Gerpen, J. et al., “Biodiesel Production Technology”,National Renewable Energy Laboratory, NREL/SR-510-36244, (Jul. 2004), 1-110.
Von Alpen, V. et al., “Compositional dependence of the electrochemical and structural parameters in the NASICON system (Na1+xSixZr2P3-xO12)”,Solid State Ionics, vol. 3/4, (1981), 215-128.
Desbois, V. International Search Report from PCT application PCT/

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