Electrolytic desulfurization of anilino sulfur compounds

Chemistry: electrical and wave energy – Processes and products

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204 73R, 564442, 564102, C25B 304, C07C 8520

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active

044040695

ABSTRACT:
Various substituted ortho-alkyl anilines are prepared by electrolytic desulfurization of various benzyl sulfides, sulfoxides and sulfones, e.g. 2-methyl-6-trifluoromethylaniline is prepared from 2-amino-3-trifluoromethylbenzyl sulfides, sulfoxides and sulfones. The processes are conducted in concentrated aqueous quaternary ammonium hydroxide, as well as in aprotic media. The substituted anilines obtained are useful as intermediates for herbicide compounds.

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