Electrolytic cell and anode for molten salt electrolysis

Details Electrolytic cell and anode for molten salt electrolysis Electrolytic cell and anode for molten salt electrolysis

1980-11-06

1983-01-25

Williams, Howard S.

Chemistry: electrical and wave energy

Apparatus

Electrolytic

204290R, 204291, 204292, 204293, C25C 304, C25C 306

Patent

active

043702163

ABSTRACT:
An uncoated ceramic anode comprising titanium having a formal valence of +4; titanium having a formal valence of +3; and a dopant which prevents at least a portion of the titanium +3 from converting to titanium +4 when the ceramic anode is at operating cell conditions. The ceramic anode may have an electrically conductive substance enclosed in its interior. The substance serves to transfer electrical energy from a power source to the ceramic member. These anodes are particularly useful when used in molten salt electrolytic cells because they give good electrolytic production rates while demonstrating exceptionally low wear rates.

REFERENCES:
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patent: 3926773 (1975-12-01), Koziol et al.
patent: 4003817 (1977-01-01), Bianchi et al.
patent: 4070504 (1978-01-01), Bianchi et al.
patent: 4071420 (1978-01-01), Foster et al.
patent: 4086157 (1978-04-01), Koziol et al.
patent: 4146438 (1979-03-01), de Nora et al.
patent: 4160069 (1979-07-01), Johnson et al.
patent: 4187155 (1980-02-01), de Nora et al.
Materials Research Bulletin, vol. 12, pp. 861-869, 1977, Pergamon Press.
Journal of Solid State Chemistry, vol. 23, pp. 399-408, (1978).
Journal of Solid State Chemistry, vol. 5, pp. 229-238, (1972).

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