Electrolyte solid polymer reticule

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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521 27, 429 33, 429192, 252 622, C25B 1308

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active

052020096

ABSTRACT:
A cross-linked polymer solid electrolyte of a polyether having amine functions cross-linked by a curing compound including two epoxy functions, and thereby defining a three-dimensional lattice which complexes an ionizable salt of the formula M.sup.+ X.sup.-, where M.sup.+ is selected from Li.sup.+, Na.sup.+, K.sup.+, Ca.sup.2+, and NH.sup.4+, and X.sup.- is selected from ClO.sub.4.sup.-, CF.sub.3 SO.sub.3.sup.-, SCN.sup.-, BF.sub.4.sup.-, I.sup.-, Br.sup.-, N.sub.3.sup.-, BH.sub.4.sup.-, CF.sub.3 CO.sub.3.sup.-, AsF.sub.6.sup.-, and PF.sub.6.sup.-, the proportion by weight of salt in the electrolyte lying in the range 5% to 40%.

REFERENCES:
patent: 4357401 (1982-11-01), Andre et al.
patent: 4654279 (1987-03-01), Bauer et al.
patent: 4830939 (1989-05-01), Lee et al.
Solid State Ionics, vol. 18/19, part I, Jan. 1986, pp. 321-325, Elsevier Science Publishers B.V., Amsterdam, Netherlands; T. Takahashi et al.: "Chemical Modification of Poly(Ethylene Imine) for Polymeric Electrolyte".

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